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The UV254Sense Probe offers a method for measuring the levels of organic compounds in water by analyzing its ultra-violet absorbance (UVA) and transmission (UVT). This device operates by continuously flowing water through a specified gap in the probe, allowing a UV254 wavelength light to pass through. It then measures the amount of light that is absorbed (indicative of UVA) and the amount that passes through (indicative of UVT).
Technological advancements in spectral analysis within the ultraviolet light spectrum have enhanced the accuracy of real-time monitoring for organic compounds in water. The UV254 analyzer, which includes capabilities for both UV transmittance and UV absorbance measurements, works by quantifying the light absorbed at a 254nm wavelength. This absorption rate is an effective metric for estimating the concentration of aromatically organic matter in water, which is useful for assessing potential disinfection byproduct (DBP) formation. Manufacturers like Pi have developed UV254 analyzers that not only assess total organic carbon (TOC) levels but are also efficient in detecting natural organic matter (NOM), common across all water sources. This is particularly relevant for understanding DBP formation risks, given the analyzers’ sensitivity to aromatic organic compounds.
The UV254Sense Probe by Pi operates using a 254nm wavelength UV LED light source. This light is directed through a water sample via a sapphire window and detected on the opposite side by a photodiode detector. The difference in the intensity of light emitted and the light received indicates the water’s UVA absorption and UVT transmission rates. This relationship is quantified according to Beer-Lambert’s law.
The UV254Sense Probe UV254 analyser has a relatively low cost for calibration and maintenance due to its lack of reagents and moving parts. Maintenance primarily involves routine cleaning and occasional recalibration using either DI or RO water. An automatic cleaning system can further reduce maintenance efforts, thereby lowering the overall cost. When considering both the acquisition and operational costs, the total cost of ownership for the UV254Sense Probe is lower than many other UV254 measuring instruments.
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UV254 measurement involves a process where light of a specific wavelength (254 nanometers) is passed through water to determine the absorption by water contaminants. These contaminants could be either particulate matter or organic compounds that have the ability to absorb at this wavelength.
UV measurement is employed in water treatment through two primary methods. Firstly, it’s used to assess the transmittance of UV light, which is crucial for deciding the intensity of UV light needed for disinfecting water. Secondly, UV measurement helps in determining the absorption of UV light, indicating the presence of organic materials in the water. This measurement often serves as a surrogate for total organic carbon (TOC), dissolved organic carbon (DOC), and chemical oxygen demand (COD), and is typically utilized for managing coagulation processes in water treatment facilities.
UVA and UVT are related measurements, though they are expressed differently. Specifically, UVA can be calculated as 2 minus the log base 10 of UVT. This indicates that while they measure similar properties, they are presented in distinct formats.
The presence of color in raw water often indicates organic materials. Consequently, both UV254 readings and water color can be indicators of organic content. While color monitoring is effective for assessing water’s appearance, it doesn’t always capture the presence of organics that lack visible coloration. Additionally, various factors, including manganese, can impart color to water, further complicating assessments based solely on color. UV254 is a more precise method for detecting aromatic organics, which are relevant because they can react with chlorine to produce undesirable disinfection by-products (DBPs). Therefore, UV254 is generally considered more advantageous for controlling coagulation processes than relying on color measurements alone.
TOC (Total Organic Carbon) represents a measurement that can be challenging and costly to perform in real-time; however, UV254 measurements may serve as an alternative indicator. This approach requires establishing a correlation between TOC and UV254 values through offline analysis, which can then be programmed into the analyzer to estimate TOC based on UV254 readings. The accuracy of this correlation largely depends on the composition of the TOC. If the TOC primarily consists of compounds that absorb at the UV254 wavelength, a strong correlation is observed. Conversely, if the TOC is composed of substances that do not absorb at this wavelength, the correlation weakens, reaching a point of no correlation when the TOC is entirely made up of non-absorbing organics. In practice, the correlation tends to be strong in the context of municipal water and wastewater treatment.
Document | Type | Size |
---|---|---|
UV254Sense Probe | Brochure | 486kB |
UV254Sense – Water | Brochure | 652kB |
UV254 Sample Strainer Unit | Technical Note | 655kB |
Correlating the UV254 Water Quality Parameters to Other Organics Parameters | Technical Note | 666kB |
Importance of Measuring UV Transmittance (UVT) for UV Disinfection | Technical Note | 445kB |
Benefits of UV Transmittance (UVT) Field Testing for Selling and Servicing UV Disinfection Systems | Technical Note | 459kB |
"We at Scottish Water have been using the excellent Pi LabSense 3 and portable UV254 instruments in the field for optimizing our Water Treatment processes for some years now. We find them easy to use and invaluable for detecting and resolving issues in a timely, efficient and effective manner. Two great pieces of kit!”
"I want to thank you and all at Process Instruments for all the assistance, information and handholding during the year. The help that was so freely given was very much appreciated. Can you please extend my appreciation to all at Pi and let me wish you all a happy, safe and wonderful Christmas and I look forward to working with you again in 2021."
"Excellent level of support and always so much more prompt than a lot of our suppliers."
"The plant can’t produce good quality water without the CoagSense."
"We've used the CRIUS® with chlorine, pH and conductivity sensors for several years and confirm quality, performance and reliability has been wholly satisfactory to date."
"We in ECM ECO Monitoring can only recommend Process Instruments products and services to all other potential clients. They have very complex portfolio of products for water quality monitoring in various types of industries, friendly attitude, very quick delivery time and prompt reaction to all our needs and inquires. Our clients especially appreciate the particle counters and sizers allowing identification of drinking water treatment problems. The Streaming Current Monitors are a great tool for optimisation of expensive chemicals.”
"Simply the best turbidity available."
"In 2019, we purchased 29 particle counters which were installed in our water plants. So far, their performance has been perfect."
"We have installed hundreds of ozone analyzers from Pi over the years. They are just accurate, reliable and require low maintenance."
"Over the last few years we've purchased chlorine and turbidity analyzers from Chemtrac and with routine calibration the probes measure the chlorine and turbidity without any issue. We are very happy with this product and would highly recommend them."
"We've been using these analyzers since 2008. They're easy to use and very stable. Calibration and maintenance is quick and simple."
"The Pi products provide excellent value for money and represent the best municipal drinking water analyzers available."
“Servicing customers is much more than just solving problems or addressing complaints and Pi does that very competently with technical and quick efforts providing a good experience."
"Pi's technical team has enabled us to be one step ahead of our competitors by adding value to our projects thanks to their fast and excellent support from the moment you first reach out.
"Going from ORP control to amperometric chlorine sensor control has undoubtedly improved the pool water immensely!"
"The Streaming Current Monitor from Pi is the best SCM I have ever used. The analyser responds quickly and has many powerful functions, which helps me save a lot of money."
“Process Instruments has a broad range of high quality and user-friendly solutions for water-industry problems. The short lead times and great customer support make Pi a reliable partner.”
"Process Instruments UK always have a high level of customer service. All our interactions with Pi have exceeded our expectations. It is always a pleasure working with you.”
"The support from Pi and its partners is superb. They go above and beyond to ensure that, not only is their equipment perfect but that the process is working great too. Five Stars!"
"Process Instruments UK always have a high level of customer service. All our interactions with Pi have exceeded our expectations. It is always a pleasure working with you.”
Process Instruments (UK) Ltd. (Pi) is an international provider of water analysis solutions established in 1998.
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